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The increased bioavailable P content significantly enhanced the capability of sediment solids to resupply labile P to porewater SRP. The stronger positive correlation between porewater soluble Fe (II) and SRP suggests that Fe redox cycling regulated internal P release. Our results suggest that dredging effectiveness will weaken over time due to the re-deposition of active P, which in turn increases the risk of sediment P release. To curb the release of sediment P, we recommend the implementation of additional in situ restoration techniques that improve the oxide layer of surface sediments and reduce sediment suspension.Veterinary antibiotics reaching the environment have become a matter of global concern, since they can cause serious negative impacts on human and ecological health. Therefore, a deep understanding of their behavior and fate once they reach the soil environment is of utmost importance to design and implement appropriate measures that could reduce their potential risks. With this aim, batch-type experiments were carried out to study competitive adsorption and desorption for three sulfonamide antibiotics (sulfadiazine -SDZ-, sulfamethazine -SMT-, and sulfachloropyridazine -SCP-) in six crop soils presenting different characteristics. The results obtained showed that sulfonamides have a low retention in soils, with average adsorption percentages of 40% for SDZ, 44% for SMT and 54% for SCP, and with desorption percentages up to 36% for SDZ and SCP and up to 29% for SMT. The retention of sulfonamides was strongly influenced by the soil organic carbon content (SOC), with higher adsorption and less desorption associated to higher SOC contents. In addition, the hydrophobicity of sulfonamides also had an influence, as higher hydrophobicity resulted in higher affinity for soils, showing the affinity sequences SDZ ~ SMT less then SCP in acid soils, and SDZ ~ SCP less then SMT in neutral soils. The results obtained in the ternary systems were very similar to those found in simple systems, indicating the absence of substantial competition for adsorption sites among the three sulfonamides. Despite the low competition among them, these antibiotics have high mobility in soils and, therefore, they imply a significant risk of contamination of water bodies, as well as of entering the food chain, generating serious hazards for human and environmental health. Therefore, fertilization of soils with sulfonamide polluted manures should be controlled, implementing new measurements for the pretreatment of manures before their application, thus contributing to a reduction of potential risks.Estuarine sediments must be dredged to allow for navigation, and where these sediments are placed after dredging depends upon guidelines based only on the total concentration of contaminants. However, resuspension events could seriously affect the mobility and speciation of contaminants, including potentially toxic trace elements stored in sediments. The effects of resuspension on the cycling of mercury (Hg) and arsenic (As) between the sediment and water column was investigated in a mesocosm study. Four experiments were conducted in three estuaries in northern Spain based on samples collected from sites which have been impacted by decommissioned Hg and As mines and periodically subjected to dredging activities. Designed to mimic the resuspension of particles, each of the experiments revealed that the release of Hg and As species does not only depend on the total concentration in the sediments (16.3-50.9 mg kg-1, for As and 0.52-5.01 mg kg-1 for Hg). The contribution from porewaters and the subsequent reductive dissolution and/or desorption appear to be the main processes responsible for the abrupt increase in dissolved Hg and As species (maximum release of 427% and 125%, respectively). In some cases, As and Hg continued to remain at high concentrations in the water column even after the experiments were completed, thus testifying to their critical persistence in the dissolved form. Conversely, at the other sites, the restoration of pre-resuspension conditions was observed only a few hours after resuspension, mainly due to the role of Fe oxy-hydroxides which provides suitable surfaces for adsorption and/or co-precipitation involving dissolved Hg (maximum removal of -58%) and As (maximum removal of -25%) species. The results of this research could be helpful to take appropriate decisions regarding dredging especially at the Nalòn estuary, where the release of dissolved As(V) and MeHg appeared to be favoured by sediment resuspension.Polybrominated diphenyl ethers (PBDEs) are ubiquitous, toxic and persistent pollutants in environments. Microalgae frequent exposed to these pollutants may possess defense mechanisms against their toxicity and have the ability to metabolize them, thus are important in bioremediation. This study investigated the mechanism of a Chlorella isolate to degrade BDE-47, a common PBDE congener, and its subcellular responses to BDE-47 stress. Results showed that 86-98% of the spiked BDE-47 was removed by Chlorella via adsorption, uptake and metabolism. BDE-47 was metabolized through debromination, hydroxylation and methoxylation. The oxidative transformation to hydroxylated products was the initial and main metabolic process. BDE-47 induced the production of hydrogen peroxide (H2O2) in cell wall, plasma membrane and chloroplast of Chlorella, and such increase was regulated by nicotinamide adenine dinucleotide phosphate oxidase and H2O2-producing peroxidases (PODs). The activity of H2O2-consuming PODs and the content of glutathione were also significantly enhanced to detoxify the oxidative stress.The potential health risk of environmental pollutant, cadmium, has become a public concern due to its widespread existence and long biological half-life. High-dose cadmium can induce various adverse outcomes, however, the chronic biological influences of cadmium at an environmental dosage and its mechanism remain largely unclear. Here, we investigated the effect of long-term exposure of cadmium at the environmental-relevant concentration on intestinal function. A chronic colitis mouse model was established through multiple cycles of dextran sulfate sodium (DSS) challenge and recovery. Selleck Roblitinib 200 nM cadmium in drinking water intensified colonic inflammation induced by DSS (histological score, DSS vs. DSS + Cd 7.4 ± 1.21 vs. 10.67 ± 0.67, P less then 0.05), including fecal occult bleeding and fecal consistency loss. Multiple inflammatory cytokines were significantly up-regulated by cadmium both in colon and plasma (P less then 0.05). In addition, intestinal integrity was compromised by cadmium. Goblet cells were markedly reduced (ctrl vs.